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Even if you only have one suitor, that character will usually confront you and demand to know what your intentions are.
If you state that you want to be with that person, you are locked into that romance for the rest of the game.
In other situations, flirting will actually be counterproductive; early flirting with Cassandra, for example, tends to lower her approval rating because she thinks you're not taking her ideals seriously.
Serious relationships (that is, relationships with long-term game consequences that may affect the endings) are limited to eight characters.
You must do this if you wish to pursue a serious romance with a different suitor.
At the most basic level, as the player-character, you can initiate flirtatious dialogue with many non-player-characters, including subjects your character cannot actually romance.